All 5 wickets in an innings:

India : 54 instances by 23 players.

England: 48 instances by 28 players.

India
Sl No	Player		Wkts/RC	Ings	Test	Venue	Year
1	Mankad	MH	8/55	1st	5th	Madras	1951-52
2	Chandrasekhar	BS	8/79	1st	1st	Delhi	1972-73
3	Amar Singh	L	7/86	1st	3rd	Madras	1933-34
4	Kumble	A	7/115	1st	2nd	Ahmedabad	2001-02
5	Amar Singh	L	6/35	1st	1st	Lord's	1936
6	Chandrasekhar	BS	6/38	2nd	3rd	The Oval	1971
7	Sharma	C	6/58	2nd	3rd	Edgbaston	1986
8	Sivaramakrishnan	L	6/64	1st	1st	Bombay	1984-85
9	Kumble	A	6/64	2nd	2nd	Madras	1992-93
10	Bedi	BS	6/71	2nd	4th	Bangalore	1976-77
11	Chandrasekhar	BS	6/76	1st	4th	Bangalore	1976-77
12	Kumble	A	6/81	2nd	1st	Mohali	2001-02
13	Chandrasekhar	BS	6/90	1st	3rd	Madras	1972-73
14	Kapil Dev	N	6/91	1st	4th	Calcutta	1981-82
15	Shinde	SG	6/91	1st	1st	Delhi	1951-52
16	Sivaramakrishnan	L	6/99	1st	2nd	Delhi	1984-85
17	Doshi	DR	6/102	1st	2nd	Old Trafford	1982
18	Durani	SA	6/105	1st	5th	Madras	1961-62
19	Sivaramakrishnan	L	6/117	2nd	1st	Bombay	1984-85
20	Bedi	BS	6/226	1st	2nd	Lord's	1974
21	Madan Lal	S	5/23	2nd	1st	Bombay	1981-82
22	Ghavri	KD	5/33	2nd	5th	Bombay	1976-77
23	Doshi	DR	5/39	1st	1st	Bombay	1981-82
24	Binny	RMH	5/40	1st	2nd	Headingley	1986
25	Durani	SA	5/47	1st	4th	Calcutta	1961-62
26	Chandrasekhar	BS	5/50	2nd	3rd	Madras	1976-77
27	Harbhajan Singh		5/51	1st	1st	Mohali	2001/02
28	Ghavri	KD	5/52	1st	1st	Bombay	1979-80
29	Bedi	BS	5/63	2nd	2nd	Calcutta	1972-73
30	Sharma	C	5/64	1st	1st	Lord's	1986
31	Chandrasekhar	BS	5/65	1st	2nd	Calcutta	1972-73
32	Kapil Dev	N	5/70	2nd	1st	Bombay	1981-82
33	Ghulam Ahmed		5/70	1st	4th	Kanpur	1951/52
34	Harbhajan Singh		5/71	2nd	2nd	Ahmedabad	2001/02
35	Surendranath		5/75	1st	5th	The Oval	1959
36	Prasad	BKV	5/76	1st	2nd	Lord's	1996
37	Madan Lal	S	5/85	1st	3rd	Delhi	1981-82
38	Borde	CG	5/88	1st	1st	Madras	1963-64
39	Desai	RB	5/89	1st	2nd	Lord's	1959
40	Mahomed Nissar		5/90	1st	1st	Bombay	1933/34
41	Gupte	SP	5/90	1st	2nd	Kanpur	1961-62
42	Mahomed Nissar		5/93	1st	1st	Lord's	1932
43	Amarnath	L	5/96	1st	2nd	Old Trafford	1946
44	Ghulam Ahmed		5/100	1st	1st	Headingley	1952
45	Mankad	MH	5/101	1st	2nd	Old Trafford	1946
46	Bedi	BS	5/110	1st	2nd	Calcutta	1976-77
47	Surendranath		5/115	1st	4th	Old Trafford	1959
48	Amarnath	L	5/118	1st	1st	Lord's	1946
49	Mahomed Nissar		5/120	1st	3rd	The Oval	1936
50	Kapil Dev	N	5/125	1st	1st	Lord's	1982
51	Chandrasekhar	BS	5/127	1st	2nd	Lord's	1967
52	Chandrasekhar	BS	5/15	1st	5th	Bombay	1972-73
53	Kapil Dev	N	5/146	1st	1st	Edgbaston	1979
54	Mankad	MH	5/196	1st	2nd	Lord's	1952
England
Sl No	Player			Ings	Test	Venue	Year
1	Trueman	FS	8/31	1st	3rd	Old Trafford	1952
2	Lever	JK	7/46	1st	1st	Delhi	1976-77
3	Botham	IT	7/48	2nd	1st	Bombay	1979-80
4	Verity	H	7/49	1st	3rd	Madras	1933-34
5	Bedser	AV	7/49	1st	1st	Lord's	1946
6	Bedser	AV	7/52	2nd	2nd	Old Trafford	1946
7	Allen	GOB	7/80	2nd	3rd	The Oval	1936
8	Illingworth	R	6/29	2nd	2nd	Lord's	1967
9	Arnold	GG	6/45	1st	1st	Delhi	1972-73
10	Tattersall	R	6/48	1st	4th	Kanpur	1951-52
11	Willis	RGD	6/53	1st	4th	Bangalore	1976-77
12	Botham	IT	6/58	1st	1st	Bombay	1979-80
13	Lock	GAR	6/65	2nd	5th	Madras	1961-62
14	Titmus	FJ	6/73	1st	5th	Kanpur	1963-64
15	Willis	RGD	6/101	2nd	1st	Lord's	1982
16	Foster	NA	6/104	1st	4th	Madras	1984-85
17	Old	CM	5/21	2nd	2nd	Lord's	1974
18	Greig	AW	5/24	2nd	2nd	Calcutta	1972-73
19	Pollard	R	5/24	1st	2nd	Old Trafford	1946
20	Willis	RGD	5/27	1st	2nd	Calcutta	1976-77
21	Bedser	AV	5/27	2nd	3rd	Old Trafford	1952
22	Statham	JB	5/31	2nd	1st	Trent Bridge	1959
23	Allen	GOB	5/35	1st	1st	Lord's	1936
24	Greenhough	T	5/35	1st	2nd	Lord's	1959
25	Botham	IT	5/35	1st	2nd	Lord's	1979
26	Bedser	AV	5/41	1st	4th	The Oval	1952
27	Allen	GOB	5/43	2nd	1st	Lord's	1936
28	Botham	IT	5/16	1st	1st	Lord's	1982
29	Trueman	FS	5/48	1st	4th	The Oval	1952
30	Nichols	MS	5/55	2nd	1st	Bombay	1933-34
31	Foster	NA	5/59	2nd	4th	Madras	1984-85
32	Lever	JK	5/59	1st	3rd	Madras	1976-77
33	Hilton	MJ	5/61	2nd	4th	Kanpur	1951-52
34	Botham	IT	5/61	2nd	1st	Bombay	1981-82
35	Langridge	J	5/63	2nd	3rd	Madras	1933-34
36	Allen	DA	5/67	1st	4th	Calcutta	1961-62
37	Giles	AF	5/67	1st	2nd	Ahmedabad	2001-02
38	Lever	P	5/70	1st	2nd	Old Trafford	1971
39	Illingworth	R	5/70	1st	3rd	The Oval	1971
40	Botham	IT	5/70	2nd	1st	Edgbaston	1979
41	Lewis	CC	5/72	2nd	1st	Edgbaston	1996
42	Sims	JM	5/73	1st	3rd	The Oval	1936
43	Price	JSE	5/73	1st	3rd	Calcutta	1963-64
44	Underwood	DL	5/84	2nd	5th	Bombay	1976-77
45	Lever	JK	5/100	1st	2nd	Bangalore	1981-82
46	Fraser	ARC	5/104	1st	1st	Lord's	1990
47	Titmus	FJ	5/116	1st	1st	Madras	1963-64
48	Fraser	ARC	5/124	1st	2nd	Old Trafford	1990